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Printable and flexible organic solar panels are promising sources of inexpensive, large-scale renewable energy, where panels can be manufactured by printing from polymer inks. There are some limitations to these types of solar cells, however. First, toxic halogenated solvents have historically been necessary to dissolve polymers to make the ink. In addition, organic solar cells typically have high rates of recombination, which limits their efficiency. Here, we use a transient photovoltage (TPV) technique to measure charge lifetimes in cells made from two different organic solvents. The first solvent is toxic, halogenated dichlorobenzene (DCB) which is typically used to make organic solar cells. The other is a less toxic, non-halogenated solvent, carbon disulfide (CS2). By varying the processing methods in this way, we find that cells made from CS2 have longer charge lifetimes and higher efficiencies than those made with DCB, as well as a different recombination rate order. Possible reasons for these differences are explored using simple analytic modeling. Our model indicates that while bimolecular recombination is dominant in both types of cells, those processed with DCB may have more trap-assisted recombination present than those processed with CS2. Overall, this work demonstrates that we may be able to decrease the toxicity of organic solar cell manufacturing and simultaneously improve the efficiency of the devices, bringing this powerful method of capturing solar energy to the forefront of sustainable energy solutions. 

In the spring period of the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition, an initiative was in place to increase the radiosounding frequency during warm air intrusions in the Atlantic Arctic sector. Two episodes with increased surface temperatures were captured during April 12–22, 2020, during a targeted observing period (TOP). The large-scale circulation efficiently guided the pulses of warm air into the Arctic and the observed surface temperature increased from −30°C to near melting conditions marking the transition to spring, as the temperatures did not return to values below −20°C. Back-trajectory analysis identifies 3 pathways for the transport. For the first temperature maximum, the circulation guided the airmass over the Atlantic to the northern Norwegian coast and then to the MOSAiC site. The second pathway was from the south, and it passed over the Greenland ice sheet and arrived at the observational site as a warm but dry airmass due to precipitation on the windward side. The third pathway was along the Greenland coast and the arriving airmass was both warm and moist. The back trajectories originating from pressure levels between 700 and 900 hPa line up vertically, which is somewhat surprising in this dynamically active environment. The processes acting along the trajectory originating from 800 hPa at the MOSAIC site are analyzed. Vertical profiles and surface energy exchange are presented to depict the airmass transformation based on ERA5 reanalysis fields. The TOP could be used for model evaluation and Lagrangian model studies to improve the representation of the small-scale physical processes that are important for airmass transformation. A comparison between MOSAiC observations and ERA5 reanalysis demonstrates challenges in the representation of small-scale processes, such as turbulence and the contributions to various terms of the surface energy budget, that are often misrepresented in numerical weather prediction and climate models. 

Abstract The THINICE field campaign, based from Svalbard in August 2022, provided unique observations of summertime Arctic cyclones, their coupling with cloud cover, and interactions with tropopause polar vortices and sea ice conditions. THINICE was motivated by the need to advance our understanding of these processes and to improve coupled models used to forecast weather and sea ice, as well as long-term projections of climate change in the Arctic. Two research aircraft were deployed with complementary instrumentation. The Safire ATR42 aircraft, equipped with the RALI (RAdar-LIdar) remote sensing instrumentation and in-situ cloud microphysics probes, flew in the mid-troposphere to observe the wind and multi-phase cloud structure of Arctic cyclones. The British Antarctic Survey MASIN aircraft flew at low levels measuring sea-ice properties, including surface brightness temperature, albedo and roughness, and the turbulent fluxes that mediate exchange of heat and momentum between the atmosphere and the surface. Long duration instrumented balloons, operated by WindBorne Systems, sampled meteorological conditions within both cyclones and tropospheric polar vortices across the Arctic. Several novel findings are highlighted. Intense, shallow low-level jets along warm fronts were observed within three Arctic cyclones using the Doppler radar and turbulence probes. A detailed depiction of the interweaving layers of ice crystals and supercooled liquid water in mixed-phase clouds is revealed through the synergistic combination of the Doppler radar, the lidar and in-situ microphysical probes. Measurements of near-surface turbulent fluxes combined with remote sensing measurements of sea ice properties are being used to characterize atmosphere-sea ice interactions in the marginal ice zone. 

This study evaluates the simulation of wintertime (15 October, 2019, to 15 March, 2020) statistics of the central Arctic near-surface atmosphere and surface energy budget observed during the MOSAiC campaign with short-term forecasts from 7 state-of-the-art operational and experimental forecast systems. Five of these systems are fully coupled ocean-sea ice-atmosphere models. Forecast systems need to simultaneously simulate the impact of radiative effects, turbulence, and precipitation processes on the surface energy budget and near-surface atmospheric conditions in order to produce useful forecasts of the Arctic system. This study focuses on processes unique to the Arctic, such as, the representation of liquid-bearing clouds at cold temperatures and the representation of a persistent stable boundary layer. It is found that contemporary models still struggle to maintain liquid water in clouds at cold temperatures. Given the simple balance between net longwave radiation, sensible heat flux, and conductive ground flux in the wintertime Arctic surface energy balance, a bias in one of these components manifests as a compensating bias in other terms. This study highlights the different manifestations of model bias and the potential implications on other terms. Three general types of challenges are found within the models evaluated: representing the radiative impact of clouds, representing the interaction of atmospheric heat fluxes with sub-surface fluxes (i.e., snow and ice properties), and representing the relationship between stability and turbulent heat fluxes. 

Abstract A remarkable, large‐amplitude, mountain wave (MW) breaking event was observed on the night of 21 June 2014 by ground‐based optical instruments operated on the New Zealand South Island during the Deep Propagating Gravity Wave Experiment (DEEPWAVE). Concurrent measurements of the MW structures, amplitudes, and background environment were made using an Advanced Mesospheric Temperature Mapper, a Rayleigh Lidar, an All‐Sky Imager, and a Fabry‐Perot Interferometer. The MW event was observed primarily in the OH airglow emission layer at an altitude of ~82 km, over an ~2‐hr interval (~10:30–12:30 UT), during strong eastward winds at the OH altitude and above, which weakened with time. The MWs displayed dominant horizontal wavelengths ranging from ~40 to 70 km and temperature perturbation amplitudes as large as ~35 K. The waves were characterized by an unusual, “saw‐tooth” pattern in the larger‐scale temperature field exhibiting narrow cold phases separating much broader warm phases with increasing temperatures toward the east, indicative of strong overturning and instability development. Estimates of the momentum fluxes during this event revealed a distinct periodicity (~25 min) with three well‐defined peaks ranging from ~600 to 800 m²/s², among the largest ever inferred at these altitudes. These results suggest that MW forcing at small horizontal scales (<100 km) can play large roles in the momentum budget of the mesopause region when forcing and propagation conditions allow them to reach mesospheric altitudes with large amplitudes. A detailed analysis of the instability dynamics accompanying this breaking MW event is presented in a companion paper, Fritts et al. (2019,https://doi.org/10.1029/2019jd030899).